Investigation of magnesium addition in ZnO matrix using group II heptahydrate

• Published in: Materials research express Vol. 8; no. 4; pp. 45011 - 45020
• Main Authors: Hussain, Hadba, Albrithen, Hamad A, Alshammari, Abeer, Alyamani, Ahmed, Bano, Nargis, Alyemni, Sarah Nasser, AlAhmary, Shareefah Ayed, Alanzi, Ali, Almutairy, Baderah Awad
• Format: Journal Article
• Language: English
• Published: Bristol IOP Publishing 01-04-2021
• Subjects: co-precipitation method; Crystallization; doping; Emission spectra; Energy gap; Grain size; Intermetallic compounds; Magnesium sulfate; Nanoparticles; Optical measurement; Photoluminescence; structure and optical properties; Wurtzite; Zinc oxide; zinc sulfate heptahydrate; ZnO
• ISSN: 2053-1591; 2053-1591
• DOI: 10.1088/2053-1591/abf1a0

Abstract
ZnO and MgZnO nanoparticles were prepared by the co-precipitation method utilizing zinc sulfate heptahydrate and magnesium sulfate heptahydrate; structural measurements were also carried out. An x-ray diffraction (XRD) study indicated that no peaks for other possible phases such as MgO or MgZn intermetallic compounds indicating pure wurtzite structure. All nanoparticles crystallized in a hexagonal wurtzite structure with different orientation diffraction peaks; the main peaks were (100), (002), and (101). Grain size (D) increased with increasing Mg concentrations. A scanning electron microscopy (SEM) analysis revealed that nanoparticle size increased by increasing the Mg concentration in a good qualitative with Scherrer equation and not only the size even the grain shape changed. In addition, optical measurements were taken infer that the band gap energy (Eg), extracted from Tauc’s plot, decreases with increasing of the Mg concentration doped, and found to be between 3.255 eV and 3.169 eV. The photoluminescence (PL) emission spectra show two peaks at the ultraviolet and green regions.