Estimation of critical properties of reaction mixtures obtained in different reaction conditions during the synthesis of biodiesel with supercritical methanol from soybean oil

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 241; pp. 418 - 432
• Main Authors: Olivares-Carrillo, Pilar, Quesada-Medina, Joaquín, Pérez de los Ríos, Antonia, Hernández-Fernández, Francisco J.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-04-2014
• Subjects: Biodiesel; Biodiesel synthesis conditions; Chemical engineering; Critical pressure estimation; Critical temperature estimation; Estimates; Group contribution; Mathematical analysis; Methyl alcohol; Soybean oil; Soybeans; Supercritical methanol; Synthesis; Thermodynamic properties; Biodiesel synthesis conditions; Supercritical methanol; Critical pressure estimation; Soybean oil; Critical temperature estimation; Group contribution
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2013.10.067

•Critical properties of 20 individual components were estimated by different methods.•Critical properties of more than 150 reaction mixtures were estimated by different methods.•Critical property data are very interesting for estimating other thermodynamic properties.
The methods of Constantinou and Gani, Ambrose, Joback, Fedors, and Klincewicz were used to estimate the critical temperatures and pressures of the pure components present during the synthesis of biodiesel from soybean oil using supercritical methanol, and the results obtained were compared. Based on the critical properties calculated for the pure components, the pseudocritical and true critical properties of the reaction mixtures obtained in different experimental reaction conditions [temperature, reaction time and methanol-to-oil molar ratio ranges of 523–623K (8–43MPa), 15–90min and 13:1–53:1, respectively] were estimated by means of Kay’s rule and the modified Prausnitz and Gunn combination, and by Li’s method, respectively. The estimated data of critical properties of the reaction mixtures appearing during the synthesis of biodiesel in supercritical methanol will be very interesting for the calculation of other thermodynamic properties, including the phase behavior of the medium.