Tack properties and adhesion mechanism of two different crosslinked polyacrylic pressure‐sensitive adhesives

• Published in: Journal of applied polymer science Vol. 138; no. 31
• Main Authors: Sasaki, Mariko, Kashihara, Yusuke, Urahama, Yoshiaki, Hirai, Tomoyasu, Fujii, Syuji, Nakamura, Yoshinobu
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 15-08-2021; Wiley Subscription Services, Inc
• Subjects: Acrylic acid; Acrylics; adhesives; Copolymers; Crosslinking; Deformation; Dynamic mechanical analysis; Fibrillation; Formability; glass transition; Isoprene rubber; Materials science; NMR; Nuclear magnetic resonance; Polymers; Rubbery plateau modulus; Storage modulus; viscosity and viscoelasticity; Wettability
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.50767

Tack properties of cross‐linked random poly(n‐butyl acrylate‐acrylic acid) (A) and poly(2‐ethylhexyl acrylate‐acrylic acid) (B) copolymers as pressure‐sensitive adhesives (PSAs) were compared by a probe tack test to know the optimal application in the industrial field. Tack increased remarkably with temperature, reached a peak, then decreased. The peak of tack appeared at higher temperature for B. Tack increased with increasing contact time and decreasing crosslinking agent level. The fracture energy at higher temperature was higher for B than A. From the observation of debonding behavior, the fibrillation occurred at the edge of probe. The wettability and deformability of PSA were larger for B than A. From a dynamic mechanical analysis, the shear storage modulus (G') in the rubbery plateau region was lower for B than for A. The good wettability and deformability were improved as a result of its lower G'. The relaxation behaviors of PSAs and vulcanized isoprene rubber were measured by 1H pulsed nuclear magnetic resonance. This technique is found to be useful for estimating the degree of intermolecular interactions. The crosslinking degree hardly influenced. The intermolecular interaction was weaker for B. This was the reason of the lower G' for B.