Methine initiated polypropylene-based disposable face masks aging validated by micromechanical properties loss of atomic force microscopy

• Published in: Journal of hazardous materials Vol. 441; p. 129831
• Main Authors: Chen, Xueqin, Zhu, Mude, Tang, Yi, Xie, Huiyuan, Fan, Xiaoyun
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 05-01-2023
• Subjects: Aging; Aging mechanism; Atomic force microscope; Chemical bond; COVID-19 - prevention & control; Disposable face masks; Humans; Masks; Micromechanical property; Microscopy, Atomic Force; Pandemics; Polypropylenes; Aging mechanism; Disposable face masks; Atomic force microscope; Chemical bond; Micromechanical property
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2022.129831

The contagious coronavirus disease-2019 pandemic has led to an increasing number of disposable face masks (DFMs) abandoned in the environment, when they are exposed to the air condition, the broken of chemical bond induced aging is inevitably occurred which meantime would cause a drastic decrease of the mechanical flexibility. However, the understanding of between chemical bond change related to aging and its micromechanical loss is limited due to the lack of refined techniques. Herein, the atomic force microscopy (AFM) technique was firstly used to observe the aging process induced by methine of the polypropylene-based DFMs. By comparing the micromechanical properties loss, the influences of humidity and light density on the DFM aging were systematically studied in the early 72 h, and it revealed that the increasing scissions number of the easiest attacked methine (Ct-H) can gradually decrease the micromechanical properties of the polypropylene (PP)-based DFM. Furthermore, the results are also validated by the in- situ FTIR and XPS analysis. This work discloses that an aging process can be initially estimated with the micromechanical changes observed by AFM, which offers fundamental data to manage this important emerging plastic pollution during COVID-19 pandemic.
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•Methine induced DFM aging is directly observed by AFM.•The changes in micro-mechanical properties during aging are quantified by AFM.•The relationship between micromechanical behavior and chemical bond is established.•Competitive formation of unsaturated bonds during aging can be observed.