Mechanical characterization of self-curing acrylic cements formulated with poly(methylmethacrylate)/poly(ϵ-caprolactone) beads

• Published in: Journal of biomedical materials research. Part B, Applied biomaterials Vol. 70B; no. 2; pp. 340 - 347
• Main Authors: Abraham, G. A., Vallo, C. I., Román, J. San, Cuadrado, T. R.
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc., A Wiley Company 15-08-2004
• Subjects: acrylic-based cements; Bone Cements - chemistry; Materials Testing; mechanical properties; Mechanics; Microscopy, Electron, Scanning; poly(methylmethacrylate); poly(ϵ-caprolactone); Polyesters - chemistry; Polymethyl Methacrylate - chemistry; Surface Properties
• ISSN: 1552-4973; 1552-4981
• DOI: 10.1002/jbm.b.30056

New acrylic‐based cements were formulated by replacing a mass fraction of 20% of poly(methyl methacrylate) (PMMA) powder by PMMA/poly(ϵ‐caprolactone) (PCL) beads (throughout this article all compositions are given as mass fractions, unless specified otherwise). PMMA/PCL beads containing 10 and 30% PCL were synthesized by suspension polymerization. Cements were prepared by replacing part of the PMMA powder of the formulation by an equivalent mass of PMMA/PCL particles. The influence of the PCL content in the beads on the mechanical behavior was assessed by testing the cements in flexure and compression. The addition of PMMA/PCL particles with 10% PCL content resulted in a marked increase in both flexural modulus and flexural strength related to the plain PMMA beads formulation. This improvement was attributed to a decrease in the cured material porosity. Conversely, by the incorporation of beads with 30% PCL content the flexural properties decreased. This behavior was attributed to the debonding of the particles from the matrix, which was revealed by SEM images. The observed compressive yield strength decrease with the increase of PCL content in the beads was attributed to a low degree of adhesion between the heterogeneous particles and the matrix as well as to the plasticizing effect of the PCL. © 2004 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater 70B: 340–347, 2004