Improved tribocorrosion behavior obtained by in-situ precipitation of Ti2C in Ti-Nb alloy

• Published in: Metals (Basel ) Vol. 12; no. 6; pp. 1 - 17
• Main Authors: Gonçalves, Vinícius Richieri Manso, Çaha, Ihsan, Alves, Alexandra Manuela Vieira Cruz Pinto, Toptan, Fatih, Rocha, Luís Augusto
• Format: Journal Article
• Language: English
• Published: Basel Multidisciplinary Digital Publishing Institute (MDPI) 01-06-2022; MDPI AG
• Subjects: Alloys; Body temperature; Chemical reactions; Corrosion effects; Corrosion tests; Electrochemical impedance spectroscopy; Hot pressing; Interfaces; Interfacial bonding; Localized corrosion; Niobium carbide; Open circuit voltage; Particle size; Particulate composites; Phase composition; Powder metallurgy; Reaction kinetics; Science & Technology; Sliding; Ti-based composites; Titanium base alloys; Transplants & implants; Tribocorrosion; United States > US
• ISSN: 2075-4701; 2075-4701
• DOI: 10.3390/met12060908

Novel in-situ Ti-based matrix composites (TMCs) were developed through the reactive hot pressing of Ti + NbC powder blends. Due to the chemical reaction that occurred in the solid-state during processing, the produced samples were composed of an Nb-rich β-Ti phase that formed a metallic matrix along with Ti 2 C as a reinforcing phase. By employing different proportions of Ti:NbC, the phase composition of the alloys was designed to contain different ratios of α-Ti and β-Ti. The present work investigated the corrosion and tribocorrosion behavior of the composites, compared to unreinforced Ti, in a phosphate-buffered solution (PBS) at body temperature. Corrosion tests included potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Tribocorrosion tests were carried out using a ball-on-plate tribometer with sliding performed at open circuit potential (OCP) and under anodic potentiostatic conditions. Results showed that the stabilization of the β phase in the matrix led to a decrease in the hardness. However, the formation of the in-situ reinforcing phase significantly improved the tribocorrosion behavior of the composites due to a load-carrying effect, lowering the corrosion tendency and kinetics under sliding. Furthermore, localized corrosion was not observed at the interface between the reinforcing phase and the matrix.
This work was supported by São Paulo Research Foundation (FAPESP), grants #2017/24300-4, #2018/00746-6 and #2019/07953-0. Also, this work was partially supported by Portuguese Foundation for Science and Technology (FCT), Portugal, under UIDB/04436/2020 project.