Thermally oxidized titania nanotubes enhance the corrosion resistance of Ti6Al4V

• Published in: Materials Science & Engineering C Vol. 59; pp. 677 - 689
• Main Authors: Grotberg, John, Hamlekhan, Azhang, Butt, Arman, Patel, Sweetu, Royhman, Dmitry, Shokuhfar, Tolou, Sukotjo, Cortino, Takoudis, Christos, Mathew, Mathew T.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01-02-2016
• Subjects: Anatase; Anodizing; Corrosion; Corrosion potential; Corrosion resistance; Current density; Hot Temperature; Nanopore; Nanotube; Nanotubes; Nanotubes - chemistry; Prosthesis Failure; Rutile; Surgical implants; Titanium; Titanium - chemistry; Titanium base alloys; Titanium dioxide; Wettability; Wettability; Corrosion; Anatase; Rutile; Nanotube; Titanium; Nanopore
• ISSN: 0928-4931; 1873-0191
• DOI: 10.1016/j.msec.2015.10.056

The negative impact of in vivo corrosion of metallic biomedical implants remains a complex problem in the medical field. We aimed to determine the effects of electrochemical anodization (60V, 2h) and thermal oxidation (600°C) on the corrosive behavior of Ti–6Al–4V, with serum proteins, at physiological temperature. Anodization produced a mixture of anatase and amorphous TiO2 nanopores and nanotubes, while the annealing process yielded an anatase/rutile mixture of TiO2 nanopores and nanotubes. The surface area was analyzed by the Brunauer–Emmett–Teller method and was estimated to be 3 orders of magnitude higher than that of polished control samples. Corrosion resistance was evaluated on the parameters of open circuit potential, corrosion potential, corrosion current density, passivation current density, polarization resistance and equivalent circuit modeling. Samples both anodized and thermally oxidized exhibited shifts of open circuit potential and corrosion potential in the noble direction, indicating a more stable nanoporous/nanotube layer, as well as lower corrosion current densities and passivation current densities than the smooth control. They also showed increased polarization resistance and diffusion limited charge transfer within the bulk oxide layer. The treatment groups studied can be ordered from greatest corrosion resistance to least as Anodized+Thermally Oxidized > Anodized > Smooth > Thermally Oxidized for the conditions investigated. This study concludes that anodized surface has a potential to prevent long term implant failure due to corrosion in a complex in-vivo environment.
•Corrosive behavior of modified Ti alloy (annealing and oxidation) was investigated.•Anodization process: a mixture of anatase/amorphous of TiO2 nanopores and nanotubes.•Annealing process: a mixture of anatase/rutile of TiO2 nanopores and nanotubes.•Corrosion resistance: Anodized+Thermally Oxidized > Anodized > Smooth > Oxidized.•The modified Ti alloy surface could have potential application for bio implants.