Two-Step, Stereoselective Hydrazidoarylation of 1,3-Cyclopentadiene

Two-Step, Stereoselective Hydrazidoarylation of 1,3-Cyclopentadiene

The product of a formal hydrazidoarylation of cyclopentadiene was obtained for the first time by palladium‐catalyzed reaction of diaza[2.2.1]bicyclic alkenes with aryl halides in the presence of triphenylarsane, sodium fluoride, and formic acid under stereoselective cleavage of a CN bond (see schem...

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Bibliographic Details
Published in:Angewandte Chemie International Edition Vol. 41; no. 18; pp. 3375 - 3378
Main Authors: Yao, Min-Liang, Adiwidjaja, Gunadi, Kaufmann, Dieter E.
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 16-09-2002
WILEY‐VCH Verlag
Subjects:
As ligands
fluoride
hydrazide
hydroarylation
palladium
Online Access:Get full text
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Summary:The product of a formal hydrazidoarylation of cyclopentadiene was obtained for the first time by palladium‐catalyzed reaction of diaza[2.2.1]bicyclic alkenes with aryl halides in the presence of triphenylarsane, sodium fluoride, and formic acid under stereoselective cleavage of a CN bond (see scheme).
Bibliography:Palladium-catalyzed reactions, part 4; part 3 ref 6. We thank BAYER AG, Leverkusen and Fond der Chemischen Industrie (Germany) for financial support.
ArticleID:ANIE3375
ark:/67375/WNG-VFRDV61H-G
istex:EA82794D7AE69BEB254E8820529323A5301AAC26
We thank BAYER AG, Leverkusen and Fond der Chemischen Industrie (Germany) for financial support.
6
Palladium‐catalyzed reactions, part 4; part 3 ref
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20020916)41:18<3375::AID-ANIE3375>3.0.CO;2-H