Leftover Kiwi Fruit Peel-Derived Carbon Dots as a Highly Selective Fluorescent Sensor for Detection of Ferric Ion

• Published in: Chemosensors Vol. 9; no. 7; p. 166
• Main Authors: Atchudan, Raji, Edison, Thomas Nesakumar Jebakumar Immanuel, Perumal, Suguna, Vinodh, Rajangam, Sundramoorthy, Ashok K., Babu, Rajendran Suresh, Lee, Yong Rok
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01-07-2021
• Subjects: Actinidia deliciosa; Agricultural wastes; Ammonium; Ammonium hydroxide; Carbon; Carbon dots; Environmental impact; ferric ion detection; Ferric ions; Fluorescence; fluorescent sensor; hydrothermal-carbonization; Iron; kiwi fruit peel; Kiwifruit; Microscopy; Morphology; Natural products; Nitrogen; Optical properties; Quantum dots; Sensors; Size distribution
• ISSN: 2227-9040; 2227-9040
• DOI: 10.3390/chemosensors9070166

Recently, the use of natural products for the synthesis of carbon dots (CDs) has received much attention. Herein, leftover kiwi (Actinidia Deliciosa) fruit peels were successfully turned into beneficial fluorescent carbon dots (KN-CDs) via the hydrothermal-carbonization route. KN-CDs 1 and KN-CDs 2 were prepared without and with ammonium hydroxide, respectively. KN-CDs 1 and KN-CDs 2 were systematically characterized by various analytical techniques. Synthesized KN-CDs showed spherical-shaped morphology with narrow size distribution and excellent optical properties with excitation-independent behaviors. The quantum yields of KN-CDs 1 and KN-CDs 2 were calculated as 14 and 19%, respectively. Additionally, the KN-CDs possess excellent prolonging and photostability. Because of the excellent optical properties of KN-CDs, they were utilized as fluorescent sensors. The strong fluorescence of the KN-CDs was selectively quenched by Fe3+ ion, and quenching behavior showed a linear correlation with the concentrations of Fe3+ ion. KN-CDs 1 and KN-CDs 2 showed the detection of Fe3+ ions within the concentration range of 5–25 µM with the detection limit of 0.95 and 0.85 µM, respectively. Based on the turn-off sensing by the detection of Fe3+ ions, KN-CDs would be a promising candidate as a selective and sensitive fluorescent sensor.