Toward Enhanced Humidity Stability of Triboelectric Mechanical Sensors via Atomic Layer Deposition

• Published in: Nanomaterials (Basel, Switzerland) Vol. 11; no. 7; p. 1795
• Main Authors: Kim, Wook, Yasmeen, Sumaira, Nguyen, Chi Thang, Lee, Han-Bo-Ram, Choi, Dukhyun
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 09-07-2021; MDPI
• Subjects: atomic layer deposition; Atomic layer epitaxy; Chemical bonds; Contact angle; Humidity; humidity stability; Moisture; Passivity; Plasma etching; Polytetrafluoroethylene; Sensors; Signal generation; Stability; surface control; Titanium oxide; Titanium oxides; triboelectric behavior; United States > US
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano11071795

Humid conditions can disrupt the triboelectric signal generation and reduce the accuracy of triboelectric mechanical sensors. This study demonstrates a novel design approach using atomic layer deposition (ALD) to enhance the humidity resistance of triboelectric mechanical sensors. Titanium oxide (TiOx) was deposited on polytetrafluoroethylene (PTFE) film as a moisture passivation layer. To determine the effective ALD process cycle, the TiOx layer was deposited with 100 to 2000 process cycles. The triboelectric behavior and surface chemical bonding states were analyzed before and after moisture exposure. The ALD-TiOx-deposited PTFE showed three times greater humidity stability than pristine PTFE film. Based on the characterization of TiOx on PTFE film, the passivation mechanism was proposed, and it was related to the role of the oxygen-deficient sites in the TiOx layer. This study could provide a novel way to design stable triboelectric mechanical sensors in highly humid environments.