Anisotropy of piezocaloric effect at ferroelectric phase transitions in ammonium hydrogen sulphate

• Published in: Journal of alloys and compounds Vol. 839; p. 155085
• Main Authors: Mikhaleva, Ekaterina A., Gorev, Mikhail V., Molokeev, Maxim S., Kartashev, Andrey V., Flerov, Igor N.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 25-10-2020; Elsevier BV
• Subjects: Anisotropy; Axes (reference lines); Crystallography; Entropy; Ferroelectric materials; Ferroelectricity; Ferroelectrics; High-pressure; Phase transition; Phase transitions; Piezocaloric effect; Thermal expansion; Thermal expansion; Piezocaloric effect; Entropy; Ferroelectrics; High-pressure; Phase transition
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2020.155085

The role of anisotropy of the thermal expansion in formation of piezocaloric effect (PCE) near ferroelectric phase transitions in NH4HSO4 was studied. Strong difference in linear baric coefficients and as a result in intensive and extensive PCE associated with the different crystallographic axes was found. PCE giving the main contribution to the barocaloric effect were determined at both phase transitions. Rather strong effect of the lattice dilatation on the tuning of PCE was observed. Comparative analysis of PCE at the phase transitions in different materials showed that NH4HSO4 can be considered as a promising solid-state refrigerant. A hypothetical cooling cycle based on alternate using uniaxial pressure along two axes was considered.
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•Strong effect of anisotropy on the piezocaloric properties of NH4HSO4.•A significant difference in signs and values of linear baric coefficients.•Large piezocaloric effects at Pc↔P1 transition at low pressure.•Effective cooling cycle by using uniaxial pressure along different axes.