Effects of Mixture Components on Sialon Composition Homogeneity on Synthesis from Kaolins

Carbothermal reduction has been combined with nitriding of kaolin with various free SiO^sub 2^ contents in the presence of additional silicon-bearing components under experimental industrial conditions to make β-sialons with Z = 0.73-3.78. It is possible to make a sialon with a given Z by means of a...

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Published in:Powder metallurgy and metal ceramics Vol. 43; no. 3-4; pp. 211 - 217
Main Authors: Vinokurov, V B, Grigor'ev, N, Bega, N D, Klimenko, L I
Format: Journal Article
Language:English
Published: New York Springer Nature B.V 01-03-2004
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Summary:Carbothermal reduction has been combined with nitriding of kaolin with various free SiO^sub 2^ contents in the presence of additional silicon-bearing components under experimental industrial conditions to make β-sialons with Z = 0.73-3.78. It is possible to make a sialon with a given Z by means of additional silicon-bearing components, and also a sialon with Z = 2 directly from raw material kaolin. X-ray diffraction indicates that the composition inhomogeneity in the sialon is dependent on the content of free SiO^sub 2^ in the mixture.[PUBLICATION ABSTRACT]
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ISSN:1068-1302
1573-9066
DOI:10.1023/B:PMMC.0000035713.25465.fb