Fabrication of Engineered Silica-Functionalized-Polyanilines Nanocomposites for Water Decontamination of Cadmium and Lead

• Published in: Journal of polymers and the environment Vol. 26; no. 9; pp. 3858 - 3876
• Main Authors: Mahmoud, Mohamed E., Fekry, Nesma A.
• Format: Journal Article
• Language: English
• Published: New York Springer US 01-09-2018; Springer Nature B.V
• Subjects: Adsorption; Adsorptivity; CADMIUM; Chemistry; Chemistry and Materials Science; Crosslinking; Decontamination; DRINKING WATER; Enthalpy; Entropy; Environmental Chemistry; Environmental Engineering/Biotechnology; Fabrication; Free energy; Industrial Chemistry/Chemical Engineering; INFRARED SPECTRA; LEAD; Materials Science; Mathematical models; NANOCOMPOSITES; NANOSCIENCE AND NANOTECHNOLOGY; Original Paper; PARTICLE SIZE; pH effects; Polyanilines; Polymer Sciences; SCANNING ELECTRON MICROSCOPY; Silica; Silicon dioxide; THERMAL GRAVIMETRIC ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; WASTE WATER; Wastewater; Water purification; Kinetic study; Divalent cadmium and lead; Nanocomposites; Adsorption isotherm models; Nanopolyaniline; Nanosilica
• ISSN: 1566-2543; 1572-8919
• DOI: 10.1007/s10924-018-1263-y

In this study, two novel functionalized silica nanocomposites were synthesized via covalent bonding with nanopolyaniline (NPANI) and crosslinked nanopolyaniline (CrossNPANI) to produce [NSi-NPANI] and [NSi-CrossNPANI], respectively. The two nanocomposites were portrayed by SEM, FT-IR, HR-TEM, BET-surface and TGA. The HR-TEM images of [NSi-NPANI] and [NSi-CrossNPANI] confirmed the particle size in the range 14.28–21.43 and 26.19–35.71 nm, respectively and these two nanocomposites were successfully applied to remove divalent cadmium and lead from solutions. As compared to nanosilica [NSi] sorbent, the maximum capacity values of the two nanocomposites for divalent cadmium and lead were identified to increase from 100–250 µmole g
−1
(pH 1.0) to 750–800 µmole g
−1
(pH 7.0) and from 400–1050 µmole g
−1
(pH 1.0) to 650–1350 µmole g
−1
(pH 6.0), at the optimum conditions. The adsorption data were compared using two and three parameter equations based on Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, Redlish-Peterson and sips models. The kinetic study of [NSi-NPANI] and [NSi-CrossNPANI] revealed that the
pseudo
-second order kinetic was the best model to explain the kinetic data for cadmium(II) and lead(II). The free energy of sorption (ΔG
o
), enthalpy (ΔH
o
), and entropy (ΔS
o
) changes were calculated to portend the nature of adsorption. Adsorptive extraction of toxic lead and cadmium from tap water and wastewater was successfully accomplished with the range of percentage recovery values 98.5–100.0 and 91.9–93.0%, respectively.