Isotopomeric Conformational Change in Anisole-Water

The deuteration of water produces the conformational change shown in the figure in the anisole⋅⋅⋅water complex. The value of the θ angle decreases from 138 to 128°, and the secondary interaction O⋅⋅⋅HMe is replaced by O⋅⋅⋅HPh.

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 44; no. 4; pp. 603 - 606
Main Authors:	Giuliano, Barbara M., Caminati, Walther
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 14-01-2005 WILEY‐VCH Verlag
Subjects:	hydrogen bonds isotope effects molecular beams molecular complexes molecular dynamics
Online Access:	Get full text
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Description
Summary:	The deuteration of water produces the conformational change shown in the figure in the anisole⋅⋅⋅water complex. The value of the θ angle decreases from 138 to 128°, and the secondary interaction O⋅⋅⋅HMe is replaced by O⋅⋅⋅HPh.
Bibliography:	istex:657C755D7A7C29EEB886B18DA60E66AEA66B9929 ark:/67375/WNG-JKVX8WC7-1 We thank the University of Bologna and the MIUR for financial support. ArticleID:ANIE200461860 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200461860