Shortwave Ultraviolet Persistent Luminescence of Sr2MgSi2O7: Pr3

• Published in: Materials Vol. 16; no. 5; p. 1776
• Main Authors: Antuzevics, Andris, Doke, Guna, Krieke, Guna, Rodionovs, Pavels, Nilova, Dace, Cirulis, Jekabs, Fedotovs, Andris, Rogulis, Uldis
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 21-02-2023; MDPI
• Subjects: afterglow; Crystal structure; Electron paramagnetic resonance; electron spin resonance (ESR); long-lasting luminescence; Luminescence; melilite; Optical properties; Phosphors; Photoluminescence; Point defects; Radiation; Short wave radiation; Software; Spectrum analysis; thermostimulated luminescence (TSL); UVC; X-rays; Germany
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma16051776

Currently, extensive research activities are devoted to developing persistent phosphors which extend beyond the visible range. In some emerging applications, long-lasting emission of high-energy photons is required; however, suitable materials for the shortwave ultraviolet (UV–C) band are extremely limited. This study reports a novel Sr2MgSi2O7 phosphor doped with Pr3+ ions, which exhibits UV–C persistent luminescence with maximum intensity at 243 nm. The solubility of Pr3+ in the matrix is analysed by X-ray diffraction (XRD) and optimal activator concentration is determined. Optical and structural properties are characterised by photoluminescence (PL), thermally stimulated luminescence (TSL) and electron paramagnetic resonance (EPR) spectroscopy techniques. The obtained results expand the class of UV–C persistent phosphors and provide novel insights into the mechanisms of persistent luminescence.