Tungsten doping effect on V2O5 thin film electrochromic performance

Electrochromic W-doped V2O5 thin films have been deposited on FTO-coated glass substrates by RF magnetron sputtering. The structural, morphological, optical and electrochromic properties of films deposited with various tungsten concentrations were studied. The increase of the doping content induces...

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Published in:	Electrochimica acta Vol. 321; p. 134743
Main Authors:	Panagopoulou, Marianthi, Vernardou, Dimitra, Koudoumas, Emmanuel, Tsoukalas, Dimitris, Raptis, Yannis S.
Format:	Journal Article
Language:	English
Published:	Oxford Elsevier Ltd 20-10-2019 Elsevier BV
Subjects:	Amorphization Band gap widening Coloration efficiency Doping Electrochromic properties Electrochromism Glass substrates Magnetic properties Magnetron sputtering Optical properties Thin films Tungsten doping Tungsten oxides Vanadium pentoxide Band gap widening Tungsten doping Vanadium pentoxide Electrochromic properties Coloration efficiency
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Abstract	Electrochromic W-doped V2O5 thin films have been deposited on FTO-coated glass substrates by RF magnetron sputtering. The structural, morphological, optical and electrochromic properties of films deposited with various tungsten concentrations were studied. The increase of the doping content induces an amorphization of the films, which contributes to an enhanced cycling performance. High W doping (resulting in WO3) values exhibit high coloration efficiency of ∼ 41 cm2 C−1at 560 nm and large transmittance modulation of 76.9% at 560 nm. Both WO3 and V2O5 are electrochromic materials with very good properties, hence their combination is of interest from both technological and fundamental perspectives.
AbstractList	Electrochromic W-doped V2O5 thin films have been deposited on FTO-coated glass substrates by RF magnetron sputtering. The structural, morphological, optical and electrochromic properties of films deposited with various tungsten concentrations were studied. The increase of the doping content induces an amorphization of the films, which contributes to an enhanced cycling performance. High W doping (resulting in WO3) values exhibit high coloration efficiency of ∼ 41 cm2 C−1at 560 nm and large transmittance modulation of 76.9% at 560 nm. Both WO3 and V2O5 are electrochromic materials with very good properties, hence their combination is of interest from both technological and fundamental perspectives.
ArticleNumber	134743
Author	Panagopoulou, Marianthi Vernardou, Dimitra Koudoumas, Emmanuel Tsoukalas, Dimitris Raptis, Yannis S.
Author_xml	– sequence: 1 givenname: Marianthi surname: Panagopoulou fullname: Panagopoulou, Marianthi email: marpanag@mail.ntua.gr organization: School of Applied Mathematical and Physical Sciences, National Technical University of Athens, 157 80, Zografou Campus, Athens, Greece – sequence: 2 givenname: Dimitra surname: Vernardou fullname: Vernardou, Dimitra organization: Center of Materials Technology and Photonics, School of Engineering, Technological Educational Institute of Crete, 71004 Heraklion, Crete, Greece – sequence: 3 givenname: Emmanuel surname: Koudoumas fullname: Koudoumas, Emmanuel organization: Center of Materials Technology and Photonics, School of Engineering, Technological Educational Institute of Crete, 71004 Heraklion, Crete, Greece – sequence: 4 givenname: Dimitris surname: Tsoukalas fullname: Tsoukalas, Dimitris organization: School of Applied Mathematical and Physical Sciences, National Technical University of Athens, 157 80, Zografou Campus, Athens, Greece – sequence: 5 givenname: Yannis S. surname: Raptis fullname: Raptis, Yannis S. organization: School of Applied Mathematical and Physical Sciences, National Technical University of Athens, 157 80, Zografou Campus, Athens, Greece
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Keywords	Band gap widening Tungsten doping Vanadium pentoxide Electrochromic properties Coloration efficiency
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Snippet	Electrochromic W-doped V2O5 thin films have been deposited on FTO-coated glass substrates by RF magnetron sputtering. The structural, morphological, optical...
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SubjectTerms	Amorphization Band gap widening Coloration efficiency Doping Electrochromic properties Electrochromism Glass substrates Magnetic properties Magnetron sputtering Optical properties Thin films Tungsten doping Tungsten oxides Vanadium pentoxide
Title	Tungsten doping effect on V2O5 thin film electrochromic performance
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