Crystal structure of bis(μ 2 -4-bromo-2-[({2-[({2-[(5-bromo-2-oxidobenzylidene)amino]ethyl}sulfanyl)sulfonyl]ethyl}imino)methyl]phenolato)dicopper(II) dimethylformamide disolvate

• Published in: Acta crystallographica. Section E, Crystallographic communications Vol. 73; no. Pt 11; pp. 1797 - 1800
• Main Authors: Rusanova, Julia A, Bederak, Dmytro
• Format: Journal Article
• Language: English
• Published: England International Union of Crystallography 01-11-2017
• Subjects: 5-bromosalicylaldehyde; crystal structure; cysteamine (2-aminoethanthiol); dinuclear copper(II) complex; Research Communications; Schiff base; Schiff base; crystal structure; cyste­amine (2-amino­ethanthiol); dinuclear copper(II) complex; 5-bromo­salicyl­aldehyde
• ISSN: 2056-9890; 2056-9890
• DOI: 10.1107/S2056989017015584

The title dinuclear copper(II) complex [Cu
(C
H
Br
N
O
S
)
] was prepared by direct synthesis of a dianionic Schiff base derived from 5-bromo-salicyl-aldehyde and cyste-amine. The discrete mol-ecules lie across inversion centers and crystallize with two di-methyl-formamide (DMF) mol-ecules of crystallization. The unique Cu
ion is four-coordinated by two tetra-dentate Schiff base ligands in a distorted square-planar N
O
environment. In the crystal, short inter-molecular S⋯Br contacts, weak C-H⋯O hydrogen bonds and intra- and inter-molecular π-π stacking inter-actions between rings of the ligand link the components into a two-dimensional network parallel to (010).