Hydrogen diffusion and hydrogen influenced critical stress intensity in an API X70 pipeline steel welded joint – Experiments and FE simulations

• Published in: International journal of hydrogen energy Vol. 37; no. 15; pp. 11474 - 11486
• Main Authors: Olden, Vigdis, Alvaro, Antonio, Akselsen, Odd M.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01-08-2012; Elsevier
• Subjects: Applied sciences; Cohesive zone modelling; Corrosion; Corrosion environments; Corrosion mechanisms; Exact sciences and technology; Fracture toughness; Hydrogen diffusion; Hydrogen embrittlement; Metals. Metallurgy; Pipeline steel; Welding; Hydrogen diffusion; Cohesive zone modelling; Pipeline steel; Welding; Hydrogen embrittlement; Fracture toughness
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2012.05.005

An API X70 pipeline steel has been investigated with respect to hydrogen diffusion and fracture mechanics properties. A finite element cohesive element approach has been applied to simulate the onset of hydrogen-induced fracture. Base metal, weld simulated heat affected zone and weld metal have been investigated. The electrochemical permeation technique was used to study hydrogen diffusion properties, while in situ fracture mechanics testing was performed in order to establish the hydrogen influenced threshold stress intensity. The average effective diffusion coefficient at room temperature was 7.60×10−11m2/s for the base metal, 4.01×10−11m2/s for weld metal and 1.26×10−11m2/s for the weld simulated heat affected zone. Hydrogen susceptibility was proved to be pronounced for the heat affected zone samples. Fracture toughness samples failed at a net section stress level of 0.65 times the yield strength; whereas the base metal samples did not fail at net section stresses lower than the ultimate tensile strength. The initial cohesive parameters which best fitted the experimental results were σc=1500MPa (3.1·σy) for the base metal, σc=1800 MPa (3.0·σy) for weld metal and σc=1840 MPa (2.3·σy) for heat affected zone. Threshold stress intensities KIc,HE were in the range 143–149MPa√m.
► Hydrogen diffusion and fracture toughness in hydrogen are tested for X70 steel. ► Laboratory experiments and finite element simulations are performed. ► The cohesive zone approach is applied to simulate the onset of hydrogen fracture. ► Base metal and weld metal have marginal susceptibility to hydrogen embrittlement. ► The heat affected zone is clearly embrittled by hydrogen.