Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution

• Published in: Nature energy Vol. 1; no. 12; p. 16184
• Main Authors: Zhao, Shenlong, Wang, Yun, Dong, Juncai, He, Chun-Ting, Yin, Huajie, An, Pengfei, Zhao, Kun, Zhang, Xiaofei, Gao, Chao, Zhang, Lijuan, Lv, Jiawei, Wang, Jinxin, Zhang, Jianqi, Khattak, Abdul Muqsit, Khan, Niaz Ali, Wei, Zhixiang, Zhang, Jing, Liu, Shaoqin, Zhao, Huijun, Tang, Zhiyong
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 28-11-2016; Nature Publishing Group
• Subjects: 639/638/161/886; 639/638/298/921; Bimetals; Density functional theory; Economics and Management; Electrocatalysts; Electrochemistry; Energy; Energy Policy; Energy Storage; Energy Systems; Heavy metals; Metal air batteries; Metal foams; Metal-organic frameworks; Metals; Nanosheets; Oxygen evolution reactions; Renewable and Green Energy; Water splitting; X-ray spectroscopy
• ISSN: 2058-7546; 2058-7546
• DOI: 10.1038/nenergy.2016.184

The design and synthesis of efficient electrocatalysts are important for electrochemical conversion technologies. The oxygen evolution reaction (OER) is a key process in such conversions, having applications in water splitting and metal–air batteries. Here, we report ultrathin metal–organic frameworks (MOFs) as promising electrocatalysts for the OER in alkaline conditions. Our as-prepared ultrathin NiCo bimetal–organic framework nanosheets on glassy-carbon electrodes require an overpotential of 250 mV to achieve a current density of 10 mA cm
−2
. When the MOF nanosheets are loaded on copper foam, this decreases to 189 mV. We propose that the surface atoms in the ultrathin MOF sheets are coordinatively unsaturated—that is, they have open sites for adsorption—as evidenced by a suite of measurements, including X-ray spectroscopy and density-functional theory calculations. The findings suggest that the coordinatively unsaturated metal atoms are the dominating active centres and the coupling effect between Ni and Co metals is crucial for tuning the electrocatalytic activity.
Efficient electrocatalysts for the oxygen–evolution reaction are desired due to their importance in applications such as water splitting and metal–air batteries. Here, the authors engineer ultrathin metal–organic frameworks that require low overpotential to generate oxygen from alkaline media.