Techno-economic comparison of 100% renewable urea production processes

• Published in: Applied energy Vol. 284; p. 116401
• Main Authors: Zhang, Hanfei, Wang, Ligang, Van herle, Jan, Maréchal, François, Desideri, Umberto
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15-02-2021
• Subjects: Biomass-to-urea; Methane-to-urea; Power-to-hydrogen; Power-to-urea; Renewable urea; Solid-oxide electrolyzer; Methane-to-urea; Biomass-to-urea; Power-to-hydrogen; Solid-oxide electrolyzer; Renewable urea; Power-to-urea
• ISSN: 0306-2619; 1872-9118
• DOI: 10.1016/j.apenergy.2020.116401

•Two renewable urea production processes are investigated techno-economically.•The overall system efficiency of biomass-to-urea may reach 39%.•Integrated biomass- and power-to-urea achieves a higher overall efficiency of 53%.•Integrated biomass- and power-to-urea enables continuous, highly-flexible operation.•Integrated biomass- and power-to-urea shows a high levelized cost of the urea.
Urea is widely used in agriculture, industry, and food, while it is also a potential fuel. Large-scale urea production relies on fossil fuels, thus there is a strong need for green urea given the increasing penetration of renewable energy sources. A potential alternative is biomass-to-urea; however, it cannot fully convert the biomass carbon into urea. To achieve full carbon conversion, innovative integrated biomass- and power-to-urea processes are designed conceptually. The two green urea production processes are evaluated techno-economically and compared with state-of-the-art methane-to-urea. The results show that the methane-to-urea achieves a system efficiency of 58% (LHV), while biomass-to-urea only has 39% (LHV) with unconverted biomass carbon of up to 60%. The integrated power- and biomass-to-urea has outstanding heat integration performance which fixes all biomass carbon into urea, with an efficiency enhanced up to 53%. Due to the electricity demand, the levelized cost of the urea of integrated biomass- and power-to-urea is 15 – 38 and 58 – 87% points higher than those of the biomass-to-urea and methane-to-urea for the scale of 10 – 60 MWth urea production. The available annual hours and electricity price of renewable electricity have a significant impact on the levelized cost of the urea. When the available annual hours decrease from 7200 to 3600 with an electricity price of 73 $/MWh, the levelized cost of urea increases on average by 13% from 51 $/GJ with the plant capacity being 10 – 60 MWth urea. However, when electricity price is reduced from 73 $/MWh to 35 $/MWh with available annual hours of 3600, the levelized cost decreases on average by 15% from 59 $/GJ with the same plant capacity.