Effect of dispersion of sepiolite in sepiolite-NBR composite on the tensile strength

• Published in: Composites. Part B, Engineering Vol. 44; no. 1; pp. 260 - 265
• Main Authors: Takei, T., Oda, R., Miura, A., Kumada, N., Kinomura, N., Ohki, R., Koshiyama, H.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01-01-2013; Elsevier
• Subjects: A. Fibers; alcohols; Applied sciences; B. Strength; Composites; D. Electron microscopy; E. Isostatic processing; Exact sciences and technology; Forms of application and semi-finished materials; Laminates; latex; Physicochemistry of polymers; Polymer industry, paints, wood; sepiolite; Technology of polymers; tensile strength; ultrasonic treatment; B. Strength; A. Fibers; D. Electron microscopy; E. Isostatic processing; Carboxylate polymer; Clay; Mechanical properties; Dispersant; Polymer; Tensile property; Nitrile rubber; Latex; Composite material; Tensile strength; Sepiolite; Polyelectrolyte
• ISSN: 1359-8368; 1879-1069
• DOI: 10.1016/j.compositesb.2012.05.034

The effect of dispersion of sepiolite in a sepiolite-NBR composite on the tensile strength of the composite was examined. Fibrous sepiolite was ultrasonically treated in distilled water with various types of dispersant. The ultrasonicated sepiolite was mixed with NBR latex to form a sepiolite-NBR complex. The tensile strength of the complex was examined to evaluate the degree of dispersion of sepiolite. The tensile strength results for the composites confirmed that a lower ultrasonication frequency produced a high strength in the composite. The tensile strength actually increased from 3 to 8MPa as a result of ultrasonication at 28kHz. To improve and stabilize the dispersion state, five kinds of dispersant were used. The addition of two dispersants in particular, ammonium polycarboxylate and amino alcohol polyphosphate, resulted in an increase of the strength from 8 to 15–16MPa. When the composites were heated at 450°C, the strengths of the composites produced with and without the dispersant were approximately 1.4–1.7 and 0.85MPa, respectively. Thus, the dispersant still affected the strength of the heated samples.