Synthesis, Structure, and Thermolysis of Tris(dimethylphenylsilyl)methyl Sulfenyl Chloride

Synthesis, Structure, and Thermolysis of Tris(dimethylphenylsilyl)methyl Sulfenyl Chloride

Sulfenyl chlorides, i.e., di-coordinated sulfur(II) chlorides are useful precursors for a variety of organic sulfur compounds. Herein, the synthesis, structure, and reactivity of a sulfenyl chloride that bears a bulky tris(dimethylphenylsilyl)methyl group on the sulfur atom are reported. The thermol...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry letters Vol. 46; no. 6; pp. 837 - 839
Main Authors: Sugamata, Koh, Ishii, Shigeru
Format: Journal Article
Language:English
Japanese
Published: Tokyo The Chemical Society of Japan 05-06-2017
Chemical Society of Japan
Subjects:
Chlorides
Organosulfur compounds
Sulfur
Sulfur compounds
Synthesis
Organosulfur compound
Sulfenyl chloride
Thermolysis
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Sulfenyl chlorides, i.e., di-coordinated sulfur(II) chlorides are useful precursors for a variety of organic sulfur compounds. Herein, the synthesis, structure, and reactivity of a sulfenyl chloride that bears a bulky tris(dimethylphenylsilyl)methyl group on the sulfur atom are reported. The thermolysis of this sulfenyl chloride resulted in the generation of the corresponding bissilylthioketone via the 1,2-elimination of chlorodimethylphenylsilane.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.170188