Gas diffusion in polyolefin foams during creep tests. Effect on impact behaviour and recovery after creep

• Published in: Cellular polymers Vol. 25; no. 4; pp. 221 - 236
• Main Authors: RODRIGUEZ-PEREZ, M. A, RUIZ-HERRERO, J. L, SOLORZANO, E, DE SAJA, J. A
• Format: Journal Article
• Language: English
• Published: Shrewsbury Rapra Technology 01-07-2006; Sage Publications Ltd. (UK); Sage Publications Ltd
• Subjects: Applied sciences; Cellular; Chemical properties; Creep; Diffusion; Exact sciences and technology; Forms of application and semi-finished materials; Materials; Mechanical properties; Polymer industry, paints, wood; Technology of polymers; Spain; Polyethylene; Closed cell; Gaseous diffusion; Transport properties; Creep; Recovery(properties); Mechanical properties; Experimental study; Fabrication property relation; Compressive stress; Impact strength; Crosslinked polymer; Foam(plastics); Olefin polymer; Diffusion coefficient
• ISSN: 0262-4893; 1478-2421
• DOI: 10.1177/026248930602500402

A method to obtain the effective diffusion coefficient of the gas contained in closed cell polyolefin foams under static loading is presented. This property is obtained from pressure decrease with time using an analytical solution of the diffusion equation. The effect of density, type of base polymer, crosslinking and sample size on the diffusion coefficient is analysed.
It has been shown that the impact behaviour of low density closed cell polyethylene based foams deteriorates after compressive creep periods and that this reduction of the cushion capabilities is directly related with the diffusion coefficient of the foams.
Moreover, the recovery of the foams after creep showed a peculiar non-homogeneous behaviour, which has been analysed. Gas diffusion during creep is the main responsible for this particular behaviour.