Metal organic frameworks-derived Fe-Co nanoporous carbon/graphene composite as a high-performance electromagnetic wave absorber

• Published in: Journal of alloys and compounds Vol. 785; pp. 765 - 773
• Main Authors: Wang, Yan, Gao, Xiang, Lin, Chenghao, Shi, Liyuan, Li, Xuanhua, Wu, Guanglei
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 15-05-2019; Elsevier BV
• Subjects: Bandwidths; Cobalt; Electromagnetic radiation; Frequency ranges; Graphene; Impedance matching; Iron; Lightweight; Magnetic properties; Metal-organic frameworks; Microwave absorbers; Microwave absorption; Microwave absorption properties; Nanoparticles; Synergistic effect; Synthesis; Thickness; Wave attenuation; Weight reduction; ZIF 67; Microwave absorption properties; ZIF 67; Graphene; Lightweight
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2019.01.271

Based on the EM wave absorption principle, superior absorbers should have the characteristics of strong attenuation constant and suitable impedance matching. In this work, a novel hierarchical composite consisting of Fe-Co nanoparticles embedded in porous carbon decorated with graphene (Fe-Co/NPC/RGO) was synthesized by a simple hydrothermal route using a Co metal organic framework (MOF) followed by calcination process. The microstructure, composition, magnetic properties and microwave absorption performances of as-synthesized samples were characterized and discussed. Compared with Fe-Co/NPC, the Fe-Co/NPC/RGO composite possessed high attenuation constant, excellent impedance matching and synergistic effect, which resulted in significant improvement in its microwave absorption properties. The optimal reflection loss (RL) was −52.9 dB at 10.1 GHz for a thickness of 2.5 mm, and the corresponding absorption bandwidth (RL < −10 dB) was almost 3.1 GHz (8.6–11.7 GHz). When the thickness was adjusted from 1.5 to 4 mm, the efficient absorption bandwidth (RL < −10 dB, 90% absorption) was as high as 13.2 GHz (over frequency range of 4.8–18 GHz). The excellent absorption performance of Fe-Co/NPC/RGO derived from MOF provides a new route for the preparation of light-weight microwave absorbers with strong absorption and wide bandwidth.
•A novel hierarchical composite of Fe-Co/NPC/RGO was fabricated successfully.•A strongest RL as low as −52.9 dB for Fe-Co/NPC/RGO is obtained with a thickness of 2.5 mm.•The effective absorption bandwidth covers the X band and Ku band.•The superior EM wave absorption mechanisms were investigated in detail.