Synthesis of Biodiesel from Canola Oil Using Heterogeneous Base Catalyst

• Published in: Journal of the American Oil Chemists' Society Vol. 84; no. 10; pp. 937 - 943
• Main Authors: D'Cruz, Amanda, Kulkarni, Mangesh G, Meher, Lekha Charan, Dalai, Ajay K
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Berlin/Heidelberg : Springer-Verlag 01-10-2007; Springer-Verlag; Springer; Springer Nature B.V
• Subjects: Alkali metals; Alumina; Barium; Biodiesel; Biodiesel fuels; Biological and medical sciences; Canola; Canola oil; Catalysts; Esters; Fat industries; Food industries; Fundamental and applied biological sciences. Psychology; Leaching; renewable energy sources; Research methodology; Solid base catalyst; transesterification; Vegetable oils; Oils and fats industry; Canola oil; Canola oil, Solid base catalyst; Alternative motor fuel; Biodiesel; Catalyst
• ISSN: 0003-021X; 1558-9331
• DOI: 10.1007/s11746-007-1121-x

A series of alkali metal (Li, Na, K) promoted alkali earth oxides (CaO, BaO, MgO), as well as K₂CO₃ supported on alumina (Al₂O₃), were prepared and used as catalysts for transesterification of canola oil with methanol. Four catalysts such as K₂CO₃/Al₂O₃ and alkali metal (Li, Na, K) promoted BaO were effective for transesterification with >85 wt% of methyl esters. ICP-MS analysis revealed that leaching of barium in ester phase was too high (~1,000 ppm) when BaO based catalysts were used. As barium is highly toxic, these catalysts were not used further for transesterification of canola oil. Optimization of reaction conditions such as molar ratio of alcohol to oil (6:1-12:1), reaction temperature (40-60 °C) and catalyst loading (1-3 wt%) was performed for most efficient and environmentally friendly K₂CO₃/Al₂O₃ catalyst to maximize ester yield using response surface methodology (RSM). The RSM suggested that a molar ratio of alcohol to oil 11.48:1, a reaction temperature of 60 °C, and catalyst loading 3.16 wt% were optimum for the production of ester from canola oil. The predicted value of ester yield was 96.3 wt% in 2 h, which was in agreement with the experimental results within 1.28%.