Comparison of the odorant composition of post-consumer high-density polyethylene waste with corresponding recycled and virgin pellets by combined instrumental and sensory analysis

• Published in: Journal of cleaner production Vol. 181; pp. 599 - 607
• Main Authors: Strangl, Miriam, Schlummer, Martin, Maeurer, Andreas, Buettner, Andrea
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 20-04-2018
• Subjects: Gas chromatography olfactometry; HDPE recycling; Mass spectrometry; Migration; Odor extract dilution analysis; Plastics; FID; 2D-HRGC–MS/O; OD; Migration; HRGC–O; HDPE recycling; Plastics; Gas chromatography olfactometry; Mass spectrometry; Odor extract dilution analysis; cOEDA
• ISSN: 0959-6526; 1879-1786
• DOI: 10.1016/j.jclepro.2018.01.137

Both, for ecological and economic reasons, the recycling of plastics for new or broader applications is currently gaining more and more attention. As high-density polyethylene (HDPE) plays an essential role in various packaging, the recycling of this material is particularly sought for. Thereby, odorous contaminants are a common obstacle when aiming at achieving high-quality HDPE recycled goods. In this respect, revealing the differences in the odorant composition of waste, recycled pellets and virgin pellets provides insights into odor sources and formation pathways and therefore supports the developing of optimized avoidance strategies. For this reason, the odor of post-consumer HDPE waste, corresponding recycled HDPE pellets and virgin HDPE granules was analyzed in the frame of the present study by comprehensive sensory analysis as well as instrumental analysis using high resolution gas chromatography-olfactometry followed by two-dimensional high resolution gas chromatography-mass spectrometry-olfactometry. In total, 32 odorous substances were identified. While some oxidation products were present in all three samples, albeit mostly with much higher smell intensity when regarding the waste and the recycled pellets, a number of terpenes as well as phenylpropanoids were found only in the HDPE waste and recycled material and, in most cases, with high sensory abundance. These odorants are likely to stem from fragrances used in cosmetics and washing/cleaning agents. Moreover, comparative odor extract dilution analysis (cOEDA) revealed that the applied conventional recycling process resulted only in a slight reduction of the odor pollution; moreover, it could be shown that no new odorants were generated to any relevant extent. Accordingly, this study shows that further optimized strategies for odorant removal from post-consumer recycled HDPE material are required.
•More than 30 odorants in post-consumer HDPE and recycled pellets were identified.•Six compounds are reported here as constituents in plastics for the first time.•Presumable sources are food spoilage and odorant migration into packaging.•Fragrances used in cosmetics, washing/cleaning agents are main odorous contaminants.•No secondary odorant formation and only low decontamination resulted from recycling.