In-situ grown nanocrystal TiO2 on 2D Ti3C2 nanosheets for artificial photosynthesis of chemical fuels

• Published in: Nano energy Vol. 51; pp. 442 - 450
• Main Authors: Xu, Yanjie, Wang, Shuai, Yang, Jun, Han, Bo, Nie, Rong, Wang, Jixian, Wang, Jianguo, Jing, Huanwang
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01-09-2018
• Subjects: 13CO2 labeling experiments; Artificial photosynthesis; Chemical fuels; CO2 reduction; TiO2/Ti3C2 heterojunction; 13CO2 labeling experiments; Chemical fuels; CO2 reduction; TiO2/Ti3C2 heterojunction; Artificial photosynthesis
• ISSN: 2211-2855
• DOI: 10.1016/j.nanoen.2018.06.086

Artificial photosynthesis of high-valued chemicals is a promising route to alleviate global warming and energy crisis. Herein, a layered hybrid heterojunction of TiO2/Ti3C2 was synthesized by a facile hydrothermal oxidation method. The TiO2/Ti3C2 heterojunction was further functionalized by imine ligands and Pd nanoparticles, and used as a photocathode in CO2 reduction for the first time. These layered TiO2/Ti3C2 heterojunction materials have narrow band gap (2.1 eV), which contributes to the absorption of visible light. In the artificial photosynthetic cell of Pd/N-TiO2/Ti3C2||BiVO4, some hydrocarbon, such as formate, methanol and ethanol, were generated efficiently. The evolution rate of total hydrocarbon was as high as 73.6 μM cm−2 h−1 (36.8 mM h−1 g−1). The hydrogen gas can be evolved in the photoelectrocatalysis cell when the external voltage provided by Si solar cell is as low as − 0.4 V, due to the high activity of the heterojunction structure. The highest apparent light quantum efficiency of artificial photosynthesis cell was 1.78% at − 1.0 V. The carbon source of products was derived from CO2, which was verified by 13CO2 labeling experiments. The experimental results suggest that the in-situ formed TiO2/Ti3C2 heterojunction materials can be employed as candidates for efficiently photoelectrocatalytic reduction of CO2 to chemical fuels.
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•In-situ grown TiO2/Ti3C2 heterojunction was firstly synthesized, functionalized and used as a photocathode in CO2 reduction.•The heterojunction benefits to the transfer of charge carries and the visible light absorption.•This APS cell of Pd/N-TiO2/Ti3C2||BiVO4 can generate formate, methanol and ethanol in a evolution rate of 36.8 mM h−1g−1.•The highest apparent light quantum efficiency was up to 1.78 % that is 4 times of plants.