Structure and catalytic activity of some soluble polyethylene glycol–peptide conjugates

Structure and catalytic activity of some soluble polyethylene glycol–peptide conjugates

Graphic Soluble catalysts for the Juliá–Colonna asymmetric epoxidation reaction have been constructed in three different ways, using NH 2-PEG-OMe as the support system: suitable solvents have been identified and it is shown that the degree of helicity of the conjugates correlates with the extent of...

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Bibliographic Details
Published in:Tetrahedron letters Vol. 45; no. 20; pp. 3885 - 3888
Main Authors: Kelly, David R., Bui, Tam T.T., Caroff, Eva, Drake, Alex F., Roberts, Stanley M.
Format: Journal Article
Language:English
Published: Elsevier Ltd 10-05-2004
Online Access:Get full text
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Summary:Graphic Soluble catalysts for the Juliá–Colonna asymmetric epoxidation reaction have been constructed in three different ways, using NH 2-PEG-OMe as the support system: suitable solvents have been identified and it is shown that the degree of helicity of the conjugates correlates with the extent of conversion and (to a lesser extent) the enantioselectivity of epoxidation.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2004.03.120