High temperature oxidation resistance of CrAlSiN coatings synthesized by a cathodic arc deposition process

• Published in: Journal of alloys and compounds Vol. 461; no. 1; pp. 336 - 341
• Main Authors: Chang, Yin-Yu, Chang, Chi-Pang, Wang, Da-Yung, Yang, Sheng-Min, Wu, Weite
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 11-08-2008; Elsevier
• Subjects: Cathodic-arc evaporation; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Hard coating; Materials science; Oxidation; Physics; Surface treatments; Hard coating; Oxidation; Cathodic-arc evaporation; Annealing; Inorganic compounds; High temperature; Hardness; Oxidation rate; Grain coarsening; Nitrides; Vapor deposition; Oxidation resistance; Silicon; Microstructure
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2007.06.084

The high-temperature oxidation behavior of the CrN and Cr–Al–Si–N coatings was studied. These coatings were deposited on silicon substrates by using a cathodic-arc deposition system with lateral rotating arc cathodes. Chromium and Al
88Si
12 cathodes were used for the deposition of Cr–Al–Si–N coatings. The deposited Cr
0.38Al
0.56Si
0.06N exhibited higher hardness of 41
±
2
GPa and higher H
3/E
*2 ratio of 0.468
GPa than CrN due to the introduction of Al and Si to form a nanocrystalline structure. For the high-temperature oxidation test, the coated samples were annealed at 800
°C in air for 2
h. The Cr
0.38Al
0.56Si
0.06N possessed much lower oxidation rate as measured by the oxide layer of the coatings. The addition of Al and Si in the coating may inhibit the formation of Cr
2N phase and grain coarsening as found in the deposited CrN coating. In addition, the coexisting Al
2O
3 and SiO
2 near the surface retarded the diffusion of oxygen into the Cr
0.38Al
0.56Si
0.06N. The deposited Cr
0.38Al
0.56Si
0.06N showed an oxidation behavior superior to the CrN. The high-temperature oxidation resistance of the CrN coatings can be improved by the formation of nanocomposite Cr–Al–Si–N.