Cd(II) removal from aqueous solution by adsorption on α-ketoglutaric acid-modified magnetic chitosan

• Published in: Applied surface science Vol. 292; pp. 710 - 716
• Main Authors: Yang, Guide, Tang, Lin, Lei, Xiaoxia, Zeng, Guangming, Cai, Ye, Wei, Xue, Zhou, Yaoyu, Li, Sisi, Fang, Yan, Zhang, Yi
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15-02-2014; Elsevier
• Subjects: Adsorbents; Adsorption; Aqueous solutions; Cadmium; Cd(II); Chitosan; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Entropy; Exact sciences and technology; Fourier transforms; Magnetic separation; Mathematical models; Physics; Surface chemistry; α-Ketoglutaric acid; α-Ketoglutaric acid; Chitosan; Cd(II); Adsorption; Magnetic separation; Aqueous solutions
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2013.12.038

•The α-ketoglutaric acid-modified magnetic chitosan exhibited fast rate on adsorption of Cd(II).•The sorption capacity for Cd(II) is high and can be described by Langmuir model.•The adsorbent shows convenient magnetic separation and effective reuse.
The present study developed an α-ketoglutaric acid-modified magnetic chitosan (α-KA-Fe3O4/CS) for highly efficient adsorption of Cd(II) from aqueous solution. Several techniques, including transmission electron microscopy (TEM), Fourier transform infrared (FTIR) and vibrating sample magnetometer (VSM), were applied to characterize the adsorbent. Batch tests were conducted to investigate the Cd(II) adsorption performance of α-KA-Fe3O4/CS. The maximum adsorption efficiency of Cd(II) appeared at pH 6.0 with the value of 93%. The adsorption amount was large and even reached 201.2mg/g with the initial Cd(II) concentration of 1000mg/L. The adsorption equilibrium was reached within 30min and commendably described by pseudo-second-order model, and Langmuir model fitted the adsorption isotherm better. Furthermore, thermodynamic parameters, free energy (ΔG), enthalpy (ΔH) and entropy (ΔS) of Cd(II) adsorption were also calculated and showed that the overall adsorption process was endothermic and spontaneous in nature because of positive ΔH values and negative ΔG values, respectively. Moreover, the Cd(II)-loaded α-KA-Fe3O4/CS could be regenerated by 0.02mol/L NaOH solution, and the cadmium removal capacity could still be kept around 89% in the sixth cycle. All the results indicated that α-KA-Fe3O4/CS was a promising adsorbent in environment pollution cleanup.