A Simple and Efficient Procedure for Oxidation of Sulfides to Sulfoxides on Hydrated Silica Gel with Ceric Ammonium Nitrate (Can) In Methylene Chloride

A Simple and Efficient Procedure for Oxidation of Sulfides to Sulfoxides on Hydrated Silica Gel with Ceric Ammonium Nitrate (Can) In Methylene Chloride

A simple, fast and efficient procedure for oxidation of sulfides to the corresponding sulfoxides with CAN mediated by hydrated silica gel in methylene chloride has been developed. To our knowledge, this is the first example of oxidation of sulfides with CAN in a non-aqueous media.

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Bibliographic Details
Published in:Synthetic communications Vol. 28; no. 16; pp. 2969 - 2981
Main Authors: Ali, Mohammed Hashmat, Leach, Damon R., Schmitz, Chad E.
Format: Journal Article
Language:English
Published: Taylor & Francis Group 01-08-1998
Online Access:Get full text
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Description
Summary:A simple, fast and efficient procedure for oxidation of sulfides to the corresponding sulfoxides with CAN mediated by hydrated silica gel in methylene chloride has been developed. To our knowledge, this is the first example of oxidation of sulfides with CAN in a non-aqueous media.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919808004876