Release of 22 elements from bottom and fly ash samples of oil shale fueled PF and CFB boilers by a two-cycle standard leaching test

• Published in: Fuel processing technology Vol. 124; pp. 147 - 154
• Main Authors: Reinik, Janek, Irha, Natalya, Steinnes, Eiliv, Urb, Gary, Jefimova, Jekaterina, Piirisalu, Eero
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01-08-2014; Elsevier
• Subjects: Air pollution caused by fuel industries; Applied sciences; Ashes; Boilers; Chromium; Combustion. Flame; Energy; Energy. Thermal use of fuels; Exact sciences and technology; Fly ash; General. Regulations. Norms. Economy; Leaching; Lead (metal); Miscellaneous; Oil shale; Oil shale ash; Release; Theoretical studies. Data and constants. Metering; Trace elements; Oil shale ash; Trace elements; Release; Cinders; Oil shale; Leaching; Standards; Characterization; Boiler; Fly ash; Trace element; Suspended particle; ICP mass spectroscopy; Fluidized bed boiler; Lixiviation; Leachate; Pulverized fuel
• ISSN: 0378-3820; 1873-7188
• DOI: 10.1016/j.fuproc.2014.03.011

Laboratory leaching tests of bottom and fly ash samples from an oil shale fueled pulverized firing (PF) and a circulated fluidized bed (CFB) boiler in 1:10 (wt/vol) suspensions of deionized water were performed. The ash samples were characterized for BETN2 specific surface area, mesopore distribution and contents of elements by ICP-MS. Water extracts were analyzed for pH, conductivity and the contents of 22 elements by ICP-MS. Several toxic metals, e.g. Tl, Mo, Sr, Cr and Pb, exhibited higher mobilization rates in fly ash samples from the PF boiler after two sequential extraction cycles compared to fly ashes from the CFB boiler. Higher mobility of trace elements in fly ash samples from the PF boiler may be explained by higher temperature in the furnace chamber of the PF boiler compared to the CFB boiler and surface characteristics of the ashes. According to the results the release of some trace elements, such as V, Cr, Ni, Cu, Zn, Mo, Cd, Ba, Tl and Pb from oil shale ash to aqueous environment is a long-term process.
•Mobility of trace elements is higher in PF fly ash compared to CFB fly ash.•Highest mobility was found for Sr, Tl and Mo in the ashes of PF boiler.•Release of several elements incl Cr, Cd, Ni and Pb is a continuous process.