New alginic acid derivatives ester for methylene blue dye adsorption: kinetic, isotherm, thermodynamic, and mechanism study

• Published in: International journal of biological macromolecules Vol. 205; pp. 651 - 663
• Main Authors: Boughrara, Lemya, Zaoui, Farouk, Guezzoul, M'hamed, Sebba, Fatima Zohra, Bounaceur, Boumediene, Kada, Seghier Ould
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 30-04-2022
• Subjects: Adsorption; Alginic acid; Chemical modification; Esterification; Methylene blue; Chemical modification; Adsorption; Alginic acid; Esterification; Methylene blue
• ISSN: 0141-8130; 1879-0003
• DOI: 10.1016/j.ijbiomac.2022.02.087

In this paper, the application of ester materials prepared by grafting different carbon chain lengths of diols in alginic acid (AA) by a simple, fast and efficient method for the adsorption of methylene blue (MB) is studied. The AA ester derivatives are characterized by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), derivative thermogravimetry (DTG), scanning electron microscopy (SEM), atomic force microscopy (AFM), and Zeta potential before and after MB adsorption. This study shows a significant improvement in the adsorption capacity of MB by AA after its esterification with a Qmax value up to 454.545 mg/g for the best adsorbent “Poly(AA-g-EG)”. The experimental data are studied according to two isothermal models (Langmuir and Freundlich) and two kinetic models (pseudo-second order and intra-particle diffusion). The adsorption of MB is also evaluated thermodynamically. An adsorption mechanism of MB is established.
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•Four different ester derivatives based on alginic acid were prepared and applied to remove Methylene Blue from water.•The ester derivatives were characterized using FTIR, TGA/DTG, SEM, Zeta potential, AFM, and XPS.•Esterification of alginic acid improves its adsorption capacity for methylene blue.•Poly(AA-g-EG) showed a maximum capacity of more than 454 mg/g.•The kinetics, isotherm, and thermodynamics of the adsorption are studied in detail.