Approaches to highly polar polymers with low glass transition temperatures. 1. Fluorinated polymers via a combination of ring-opening metathesis polymerisation and hydrogenation

The synthesis and hydrogenation of two fluorinated polymers is described. The products were characterised through a detailed study of their 1H-, 13C- and 19F-NMR spectra, together with thermal and GPC analysis. Hydrogenation resulted in a significant lowering of the glass transition temperatures of...

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Bibliographic Details
Published in:	Polymer (Guilford) Vol. 44; no. 19; pp. 6111 - 6121
Main Authors:	James Feast, W, Gimeno, Miquel, Khosravi, Ezat
Format:	Journal Article
Language:	English
Published:	Oxford Elsevier Ltd 01-09-2003 Elsevier
Subjects:	Applied sciences Exact sciences and technology Fluoropolymers Hydrogenation Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts ROMP Hydrogenation ROMP Fluoropolymers Ring opening polymerization Molecular structure Fluorine containing polymer Complex catalyst polymerization Experimental study Saturated polymer Chemical modification Metathesis polymerization Preparation Norbornene derivative polymer Unsaturated polymer Microstructure
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Summary:	The synthesis and hydrogenation of two fluorinated polymers is described. The products were characterised through a detailed study of their 1H-, 13C- and 19F-NMR spectra, together with thermal and GPC analysis. Hydrogenation resulted in a significant lowering of the glass transition temperatures of the polymers.
Bibliography:	ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23
ISSN:	0032-3861 1873-2291
DOI:	10.1016/S0032-3861(03)00551-2