Synthesis and photophysical studies of through-space conjugated [2.2]paracyclophane-based naphthalene fluorophores

Synthesis and photophysical studies of through-space conjugated [2.2]paracyclophane-based naphthalene fluorophores

In this work we report a straightforward method for the synthesis of a new class of small organic fluorophores bearing both [2.2]paracyclophane and naphthalene subunits using an intramolecular dehydrogenative Diels–Alder reaction as a key step. These compounds are characterized by a compact three-di...

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Bibliographic Details
Published in:RSC advances Vol. 7; no. 80; pp. 50472 - 50476
Main Authors: Benedetti, E., Delcourt, M.-L., Gatin-Fraudet, B., Turcaud, S., Micouin, L.
Format: Journal Article
Language:English
Published: Royal Society of Chemistry 2017
Subjects:
Analytical chemistry
Chemical Sciences
or physical chemistry
Organic chemistry
Theoretical and
Online Access:Get full text
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Summary:In this work we report a straightforward method for the synthesis of a new class of small organic fluorophores bearing both [2.2]paracyclophane and naphthalene subunits using an intramolecular dehydrogenative Diels–Alder reaction as a key step. These compounds are characterized by a compact three-dimensional structure as well as through-space conjugated push–pull systems, and possess interesting spectroscopic characteristics that may be useful for the development of innovative chemical probes and optical sensors.
ISSN:2046-2069
2046-2069
DOI:10.1039/C7RA10038H