Direct Synthesis of Pseudo-Disaccharides by Rearrangement of Unsaturated Disaccharides

Direct Synthesis of Pseudo-Disaccharides by Rearrangement of Unsaturated Disaccharides

The series of unsaturated disaccharides 10–14undergo stereoselective reductive rearrangement with TIBAL (triisobutylaluminium) to afford (1→4) and (1→6) ether‐linked pseudo‐disaccharides 2–9.

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Bibliographic Details
Published in:European journal of organic chemistry Vol. 1999; no. 9; pp. 2103 - 2117
Main Authors: Pearce, Alan James, Sollogoub, Matthieu, Mallet, Jean-Maurice, Sinaÿ, Pierre
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag GmbH 01-09-1999
WILEY‐VCH Verlag GmbH
Subjects:
5′a-Carbadisaccharides
Carbohydrates
Cyclohexane
Rearrangements
Triisobutylaluminium
Online Access:Get full text
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Description
Summary:The series of unsaturated disaccharides 10–14undergo stereoselective reductive rearrangement with TIBAL (triisobutylaluminium) to afford (1→4) and (1→6) ether‐linked pseudo‐disaccharides 2–9.
Bibliography:istex:FD362BE2193E6E4B7ED1AA7F523FC23C61478AD3
ArticleID:EJOC2103
ark:/67375/WNG-5JSSCNMT-P
ISSN:1434-193X
1099-0690
DOI:10.1002/(SICI)1099-0690(199909)1999:9<2103::AID-EJOC2103>3.0.CO;2-K