Performance evaluation of polymer-marine biomass based bionanocomposite for the adsorptive removal of malachite green from synthetic wastewater

• Published in: Environmental research Vol. 204; no. Pt B; p. 112132
• Main Authors: Sarojini, G., Venkatesh Babu, S., Rajamohan, N., Rajasimman, M.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier Inc 01-03-2022
• Subjects: Adsorption; Biomass; Hydrogen-Ion Concentration; Isotherm; Kinetics; Malachite green; Mechanism; Nanocomposite; Polymers; Rosaniline Dyes; Thermodynamics; Waste Water; Water Pollutants, Chemical - analysis; Isotherm; Nanocomposite; Adsorption; Mechanism; Malachite green
• ISSN: 0013-9351; 1096-0953
• DOI: 10.1016/j.envres.2021.112132

In this experimental investigation, feasibility and performance of a polymer hybrid bio-nano composite were evaluated to remove malachite green (MG) under controlled environment conditions. The polymer hybrid bio-nanocomposite was characterized using FTIR, SEM and EDS. The influence of operating variables, namely effect of pH (2–11), nanocomposite dosage (20–100 mg), initial MG concentration (10– 200 mg/L), contact time (10–120 min) and temperature (298–318 K) were explored. The maximum removal efficiency (RE) of 99.79% was achieved at neutral pH at the dosage level of 50 mg with the initial MG concentration of 150 mg/L in 40 min. The equilibrium results revealed that the adsorption of MG data fitted to Langmuir isotherm (R2 > 0.970) indicating monolayer adsorption. The maximum adsorption capacity of polymer hybrid nanocomposite was found to be 384.615 mg/g. Kinetic studies were performed using five kinetic models and results showed the pseudo second order model fitted very well with the MG adsorption data (R2 > 0.990). The thermodynamic results confirmed that MG adsorption onto polymer hybrid nanocomposite is feasible and (ΔS ͦ = 0.2893 kJ/mol K), spontaneous (ΔH ͦ = 81.103 kJ/mol K) and exothermic (ΔG ͦ < 0). A mechanism is also proposed for the removal of MG using the polymer nanocomposite and identified that electrostatic attraction and hydrogen bonding as the major mechanism for removal of MG. FTIR results confirmed the presence of carboxyl (-COO) and hydroxyl (-OH) groups which helped in effective binding of cationic dye. The overall results revealed that polymer nanocomposite could be used as a potential adsorbent for removing MG from aqueous solution.
•Synthesized polymer based bio-nanocomposite was used for sorptive removal of MG dye.•Polymer based bio-nanocomposite removes 384.61 mg/g of MG dye.•Adsorption of MG follows Langmuir and Pseudo second order kinetics.•Thermodynamic study reveals that the process is feasible, spontaneous and exothermic.•Mechanism of MG removal was found to be electrostatic interaction and ion-exchange.