Surface resonance transition of roughened Cu(1 1 0)

The temperature dependence of the reflection anisotropy spectroscopy (RAS) of a Cu(1 1 0) surface has been studied over the temperature range 700–1000 K. Because of the roughening transition at 900 K, the bimodal feature at 4.2 eV for a clean surface shifted to 4.3 eV on annealing. A significant dec...

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Bibliographic Details
Published in:Surface science Vol. 601; no. 9; pp. 2012 - 2016
Main Authors: Zeybek, O., Davarpanah, A.M., Martin, D.S., Barrett, S.D.
Format: Journal Article
Language:English
Published: Lausanne Elsevier B.V 01-05-2007
Amsterdam Elsevier Science
New York, NY
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Summary:The temperature dependence of the reflection anisotropy spectroscopy (RAS) of a Cu(1 1 0) surface has been studied over the temperature range 700–1000 K. Because of the roughening transition at 900 K, the bimodal feature at 4.2 eV for a clean surface shifted to 4.3 eV on annealing. A significant decrease in intensity of the same energy level was also observed with increasing annealing temperature. In the annealing temperature range 700–1000 K, anharmonic behavior is expected to be the predominant process of atomic disordering at the surface. Changes in the RAS of Cu(1 1 0) as a result of thermal processing can be understood in terms of the associated changes in surface states. The RAS signal for a surface resonance transition at 4.2 eV is associated with monoatomic [0 0 1] steps.
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content type line 23
ISSN:0039-6028
1879-2758
DOI:10.1016/j.susc.2007.02.029