Sensitivity of the Drift-Diffusion Approach in Estimating the Power Conversion Efficiency of Bulk Heterojunction Polymer Solar Cells

• Published in: Energies (Basel) Vol. 10; no. 3; p. 285
• Main Authors: Fallahpour, Amir, Di Carlo, Aldo, Lugli, Paolo
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 2017
• Subjects: Approximation; Complexity; Complications; Diffusion; drift-diffusion; Efficiency; Energy conversion efficiency; Estimation; Excitons; Heterojunctions; Material properties; Model accuracy; modelling and simulation; organic semiconductor; Parameter estimation; Parameter sensitivity; Photovoltaic cells; Physical properties; Polymers; power conversion efficiency (PCE); Process parameters; Simulation; Solar cells; Solar power
• ISSN: 1996-1073; 1996-1073
• DOI: 10.3390/en10030285

There are numerous theoretical approaches to estimating the power conversion efficiency (PCE) of organic solar cells (OSCs), ranging from the empirical approach to calculations based on general considerations of thermodynamics. Depending on the level of ion and model assumptions, the accuracy of PCE estimation and complexity of the calculation can change dramatically. In particular, PCE estimation with a drift-diffusion approach (widely investigated in the literature), strongly depends on the assumptions made for the physical models and optoelectrical properties of semiconducting materials. This has led to a huge deviation as well as complications in the analysis of simulated results aiming to understand the factors limiting the performance of OSCs. In this work, we intend to highlight the complex relation between mobility, exciton dynamics, nanoscale dimension, and loss mechanisms in one framework. Our systematic analysis represents key information on the sensitivity of the drift-diffusion approach, to estimate how physical parameters and physical processes bind the PCE of the device under the influence of structure, contact, and material layer properties. The obtained results ultimately led to recommendations for putting effort into certain properties to get the most out of avoidable losses, presented the impact and importance of modification of material properties, and in particular, recommended to what degree the design of new material could improve OSC performance.