Introduction of cadmium chloride additive to improve the performance and stability of perovskite solar cells

• Published in: RSC advances Vol. 12; no. 32; pp. 2461 - 247
• Main Authors: Mohammed, Mustafa K. A, Jabir, Majid S, Abdulzahraa, Haider G, Mohammed, Safa H, Al-Azzawi, Waleed Khaild, Ahmed, Duha S, Singh, Sangeeta, Kumar, Anjan, Asaithambi, S, Shekargoftar, Masoud
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 14-07-2022; The Royal Society of Chemistry
• Subjects: Cadmium chloride; Charge transport; Chemistry; Clean energy; Control equipment; Energy conversion efficiency; Hydrophobicity; Maximum power; Performance enhancement; Perovskites; Photovoltaic cells; Solar cells; Stability
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d2ra03776a

With the increase in the importance of using green energy sources to meet the world's energy demands, attempts have been made to push perovskite solar cell technology toward industrialization all around the world. Improving the properties of perovskite materials as the heart of PSCs is one of the methods to fabricate favorable photovoltaic (PV) solar cells based on perovskites. Here, cadmium chloride (CdCl
2
) was used as an additive source for the perovskite precursor to improve its PV properties. Results indicated CdCl
2
improves the perovskite growth and tailors its crystalline properties, suggesting boosted charge transport processes in the bulk and interfaces of the perovskite layer with electron-hole transport layers. Overall, by incorporation of 1.0% into the MAPbI
3
layer, a maximum power conversion efficiency of 15.28% was recorded for perovskite-based solar cells, higher than the 12.17% for the control devices. The developed method not only improved the PV performance of devices but also boosted the stability behavior of solar cells due to the passivated domain boundaries and enhanced hydrophobicity in the CdCl
2
-based devices.
With the increase in the importance of using green energy sources to meet the world's energy demands, attempts have been made to push perovskite solar cell technology toward industrialization all around the world.