Practical and efficient ipso-iodination of arylboronic acids via KF/I2 system

Practical and efficient ipso-iodination of arylboronic acids via KF/I2 system

[Display omitted] A facile and effective iododeboronation of variously substituted aryl and heteroarylboronic acids through activation and subsequent ipso-introduction of iodine is presented. The use of KF and I2 at 80°C in 1,4-dioxane furnishes iodinated compounds in high yields.

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Bibliographic Details
Published in:Tetrahedron letters Vol. 56; no. 9; pp. 1122 - 1123
Main Authors: Tramutola, Francesco, Chiummiento, Lucia, Funicello, Maria, Lupattelli, Paolo
Format: Journal Article
Language:English
Published: Elsevier Ltd 25-02-2015
Subjects:
Boronic acids
Deboronation
Iodination
Iodoarenes
Iodination
Iodoarenes
Deboronation
Boronic acids
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Description
Summary:[Display omitted] A facile and effective iododeboronation of variously substituted aryl and heteroarylboronic acids through activation and subsequent ipso-introduction of iodine is presented. The use of KF and I2 at 80°C in 1,4-dioxane furnishes iodinated compounds in high yields.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2015.01.040