The Effect of Irradiation Sterilization on Poly(Lactic) Acid Films

• Published in: Journal of polymers and the environment Vol. 29; no. 2; pp. 460 - 471
• Main Authors: Benyathiar, Patnarin, Selke, Susan E., Harte, Bruce R., Mishra, Dharmendra K.
• Format: Journal Article
• Language: English
• Published: New York Springer US 01-02-2021; Springer Nature B.V
• Subjects: Carbon dioxide; Chemistry; Chemistry and Materials Science; Crystallization; Electron beams; Elongation; Environmental Chemistry; Environmental Engineering/Biotechnology; Gamma irradiation; Industrial Chemistry/Chemical Engineering; Ionizing radiation; Irradiation; Materials Science; Mechanical properties; Melt temperature; Modulus of elasticity; Molecular weight; Original Paper; Permeability; Polymer Sciences; Radiation dosage; Sterilization; Surface tension; Tensile strength; Water vapor; Packaging sterilization; Ionizing radiation; PLA; Packaging material properties; Bio-based material
• ISSN: 1566-2543; 1572-8919
• DOI: 10.1007/s10924-020-01892-8

Ionizing radiation is known to cause the deterioration of polymeric materials. In this study, the goal was to determine the effect of gamma and E-beam radiation on poly(lactic) acid (PLA) film at irradiation dosages of 1 to 30 kGy and on post-irradiated PLA after 9-months storage. The physical, chemical, mechanical, thermal, and permeability properties were investigated. Ionizing radiation of the commercial PLA film resulted in a decrease in molecular weight, crystallization temperature and melting temperature T
c
and T
m
, which suggested a degradation of PLA by irradiation. Irradiation had no effect on the color of the PLA film. The surface tension of PLA was decreased by gamma irradiation at dose of 1–10 kGy and E-beam irradiation at dose of 1–5 kGy. A decrease in the tensile strength, break elongation and elastic modulus was found for the gamma and E-beam irradiated PLA. Irradiation resulted in a decrease in water vapor and carbon dioxide permeability of PLA while there was no effect on oxygen permeability.