Aggregation-induced emission: mechanistic study of the clusteroluminescence of tetrathienylethene

• Published in: Chemical science (Cambridge) Vol. 8; no. 4; pp. 2629 - 2639
• Main Authors: Viglianti, Lucia, Leung, Nelson L C, Xie, Ni, Gu, Xinggui, Sung, Herman H Y, Miao, Qian, Williams, Ian D, Licandro, Emanuela, Tang, Ben Zhong
• Format: Journal Article
• Language: English
• Published: England 01-04-2017
• Subjects: Aggregates; Behavior; Crystals; Derivatives; Emission; Emission analysis; Luminescence; Photoluminescence
• ISSN: 2041-6520; 2041-6539
• DOI: 10.1039/c6sc05192h

In this work we have investigated the aggregation-induced emission (AIE) behaviour of 1,1,2,2-tetra(thiophen-2-yl)ethene (tetrathienylethene, TTE). The semi-locked and fully-locked derivatives (sl-TTE and fl-TTE) have been synthesized to better understand the mechanism behind the solid state photoluminescence of TTE. TTE is a typical AIEgen and its luminescence can be explained through the mechanistic understanding of the restriction of intramolecular motions (RIM). The emissive behaviour of TTE in the THF/water aggregates and crystal state have also been studied, revealing a remarkable red-shift of 35 nm. A similar red-shift emission of 37 nm from the THF/water aggregates to the crystal state is also observed for (
)-1,2-di(thiophen-2-yl)ethene (
-dithienylethene, DTE). Crystal analysis has revealed that the emission red-shifts are ascribable to the presence of strong sulfur-sulfur (S···S) intra- and intermolecular interactions that are as close as 3.669 Å for TTE and 3.679 Å for DTE. These heteroatom interactions could help explain the photoluminescence of non-conventional luminophores as well as the luminescence of non-conjugated biomacromolecules.