Role of Halide Ions for Controlling Morphology of Copper Nanocrystals in Aqueous Solution

• Published in: ChemistrySelect (Weinheim) Vol. 2; no. 17; pp. 4655 - 4661
• Main Authors: Tang, Zengmin, Kwon, Hyunguk, Yi, Minyoung, Kim, Kyungpil, Han, Jeong Woo, Kim, Woo‐Sik, Yu, Taekyung
• Format: Journal Article
• Language: English
• Published: 12-06-2017
• Subjects: aqueous-phase synthesis; Halide ion; morphology control; nanoplates; simulation
• ISSN: 2365-6549; 2365-6549
• DOI: 10.1002/slct.201701173

This paper reports the influence of halide ions on the morphology‐controlled synthesis of Cu nanocrystals in the aqueous phase. Cu nanocrystals with controlled shapes, including 2D plates, 1D wires, and 3D polyhedral particles were obtained by a reduction reaction between Cu‐halide and ascorbic acid, and branched polyethyleneimine (BPEI) was used as a stabilizing agent in the process. Density functional theory (DFT) calculations showed that this morphological control was caused by the selective adsorption of halide ions depending on the facets of the Cu nanocrystals. The thickness and lateral size of the Cu nanoplates were tuned easily using a co‐stabilizer, the addition of Br− ions, and varying the pH of the reaction solution. Furthermore, the resulting Cu nanocrystals possessed great stability, showing very little change after exposure to the ambient atmosphere for 40 days. Overall, this synthetic procedure could be a potential method for the mass synthesis of morphology‐controlled Cu nanocrystals for industrial applications because of the superior reaction conditions, such as the air atmosphere, low reaction temperature, water‐phase‐based synthetic condition as well as the use of nontoxic and inexpensive reagents.
A novel protocol to synthesize the Cu nanocrystals with a controlled morphology is reported by varying the types of halide ions (Br−, Cl−, and F−) in the Cu precursor in an aqueous solution. This behavior was caused by the selective adsorption of halide ions depending on the facets of the Cu nanocrystals.