Multiwalled Carbon Nanotubes Supported Pd(II)-Salen Complex: An Effective, Phosphorous-Free, and Reusable Heterogeneous Precatalyst for the Synthesis of Diaryl Ketones

The Suzuki–Miyaura cross‐coupling reaction of aroyl chlorides and arylboronic acids has been carried out efficiently in the presence of Pd(II)‐salen@MWCNTs as an air‐moisture stable precatalyst. The influence of various parameters, such as solvent, temperature, and base on the reaction system, was s...

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Bibliographic Details
Published in:	Helvetica chimica acta Vol. 99; no. 9; pp. 747 - 752
Main Authors:	Mohammadi, Elmira, Hajilou, Zahra, Movassagh, Barahman
Format:	Journal Article
Language:	English
Published:	Zürich Blackwell Publishing Ltd 01-09-2016 Wiley Subscription Services, Inc
Subjects:	Aromatic ketones Aroyl chlorides Arylboronic acids Multiwalled carbon nanotubes Nanotubes Palladium complex Suzuki-Miyaura coupling
Online Access:	Get full text
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Summary:	The Suzuki–Miyaura cross‐coupling reaction of aroyl chlorides and arylboronic acids has been carried out efficiently in the presence of Pd(II)‐salen@MWCNTs as an air‐moisture stable precatalyst. The influence of various parameters, such as solvent, temperature, and base on the reaction system, was studied. Furthermore, the catalyst can be easily recovered quantitatively by a simple filtration and reused for three consecutive runs without significant loss of its activity.
Bibliography:	istex:A2982E0417ED6A46EF11432C70CE2661F994680D K. N. Toosi University of Technology Research Council ArticleID:HLCA201600161 ark:/67375/WNG-1N1DWBMG-0
ISSN:	0018-019X 1522-2675
DOI:	10.1002/hlca.201600161