Crystal structure of dibromido( N , N -dimethylformamide-κ O ){2-(1 H -indol-3-yl)- N -[(quinolin-2-yl-κ N )methylidene]ethanamine-κ N }cadmium

• Published in: Acta crystallographica. Section E, Crystallographic communications Vol. 71; no. 2; pp. m31 - m32
• Main Authors: Faizi, Md. Serajul Haque, Sharkina, Natalia O., Davydenko, Yuliya M.
• Format: Journal Article
• Language: English
• Published: International Union of Crystallography 01-02-2015
• Subjects: CdII complex with IQME; crystal structure; N—H...Br interactions; quinolinyl-containing Schiff base
• ISSN: 2056-9890; 2056-9890
• DOI: 10.1107/S2056989015000778

In the mononuclear title complex, [CdBr
2
(C
20
H
17
N
3
)(C
3
H
7
NO)], synthesized from the quinoline-derived Schiff base 2-(1
H
-indol-3-yl)-
N
-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd
2+
atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one dimethylformamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the Cd
II
atom from the equatorial plane being 0.046 (1) Å. An intramolecular C—H...Br interaction occurs. In the crystal, N—H...Br interactions generate [101] chains.