Flower-like magnetite nanoparticles with unfunctionalized surface as an efficient catalyst in photo-Fenton degradation of chemical dyes

• Published in: Applied surface science Vol. 638; p. 158127
• Main Authors: Łoński, Sylwester, Łukowiec, Dariusz, Barbusiński, Krzysztof, Babilas, Rafał, Szeląg, Bartosz, Radoń, Adrian
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 30-11-2023
• Subjects: Dye removal; Logistic regression; Magnetite nanoparticles; photo-Fenton; Sodium percarbonate; Magnetite nanoparticles; Logistic regression; Sodium percarbonate; photo-Fenton; Dye removal
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2023.158127

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•Flower-like magnetite nanocatalyst was synthesized using the co-precipitation method and solid-state Fe3+ precursor.•The applicability of magnetite nanoflowers in heterogeneous photo-Fenton reactions using sodium percarbonate was confirmed.•Logistic regression models confirmed the role of sodium percarbonate and nanocatalyst concentration on the decolorization efficiency.•The optimized reaction allowed to decolorize of 97.3% of Lissamine Green B and 61.8% of Naphthol Green B.•The unfunctionalized surface of magnetite nanoparticles is a much more critical parameter than their size.
Flower-like magnetite nanoflowers (Fe3O4 NFs) were synthesized in this study using a new, highly scalable, modified co-precipitation method. The heterogeneous photo-Fenton process was optimized for the degradation of Rhodamine B using sodium percarbonate as an alternative source of H2O2. The low dosage of NPs (0.6 mg/ml) can ensure the high Rhodamine B degradation of about 93.6% at pH 4 and sodium percarbonate concentration of 8.3 mg/ml. Studies confirm the high cyclic stability of Fe3O4 NFs and the possibility of using optimized reaction condition in the degradation of Lissamine Green B (97.3%) and Naphthol Green B (61.8%). Moreover, it was confirmed that O2̇− and HO∙ are the primary radicals oxidizing Rhodamine B, while the ultrafast Lissamine Green B degradation corresponds to their oxidation by O2̇−. Finally, surface functionalization was confirmed as one of the most critical parameters in designing catalysts for heterogeneous photo-Fenton processes. The study confirms that in the case of surface functionalization, the degradation of dyes is slowed down (reduction of active sites on the magnetite surface by the organic molecules). Accordingly, the ultrafine, spherical-shaped magnetite nanoparticles functionalized by thrietylene glycol were characterized by above 3 times lower catalytic activity than unfunctionalized Fe3O4 NFs.