In Situ Li‐Plating Diagnosis for Fast‐Charging Li‐Ion Batteries Enabled by Relaxation‐Time Detection

• Published in: Advanced materials (Weinheim) Vol. 35; no. 42; pp. e2301881 - n/a
• Main Authors: Xu, Lei, Xiao, Ye, Yang, Yi, Xu, Rui, Yao, Yu‐Xing, Chen, Xiao‐Ru, Li, Ze‐Heng, Yan, Chong, Huang, Jia‐Qi
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 19-10-2023
• Subjects: Charge transfer; Charging; Cognition; Diagnosis; fast‐charging; High temperature; Li plating; Lithium-ion batteries; Li‐ion batteries; Low temperature; Plating; Relaxation time; relaxation time constant; safe window; Stress relaxation tests; Time constant
• ISSN: 0935-9648; 1521-4095
• DOI: 10.1002/adma.202301881

The Li‐plating behavior of Li‐ion batteries under fast‐charging conditions is elusive due to a lack of reliable indicators of the Li‐plating onset. In this work, the relaxation time constant of the charge‐transfer process (τCT) is proposed to be promising for the determination of Li‐plating onset. A novel pulse/relaxation test method enables rapid access to the τCT of the graphite anode during battery operation, applicable to both half and full batteries. The diagnosis of Li plating at varying temperatures and charging rates enriches the cognition of Li‐plating behaviors. Li plating at low temperatures and high charging rates can be avoided because of the battery voltage limitations. Nevertheless, after the onset, severe Li plating evolves rapidly under harsh charging conditions, while the Li‐plating process under benign charging conditions is accompanied by a simultaneous Li‐intercalation process. The quantitative estimates indicate that Li plating at high temperatures/high charging rates leads to more irreversible capacity losses. This facile method with rational scientific principles can provide inspiration for exploring the safe boundaries of Li‐ion batteries.
An effective indicator of Li‐plating onset is urgently needed to investigate the safety window of Li‐ion batteries. This work demonstrates that the relaxation time constant of the charge‐transfer process is promising for determining Li‐plating onset. A relaxation‐time detection method is proposed, allowing in situ diagnosis of the Li‐plating behavior in fast‐charging Li‐ion batteries.