Preparation and Characterization of Gamma Irradiated Sugar Containing Starch/Poly (Vinyl Alcohol)-Based Blend Films

• Published in: Journal of polymers and the environment Vol. 19; no. 4; pp. 1013 - 1022
• Main Authors: Parvin, Fahmida, Khan, Mubarak A., Saadat, A. H. M., Khan, M. Anwar H., Islam, Jahid M. M., Ahmed, Mostak, Gafur, M. A.
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01-12-2011; Springer Nature B.V
• Subjects: Biodegradable materials; Biodegradation; Blends; Chemistry; Chemistry and Materials Science; Differential thermal analysis; Environmental Chemistry; Environmental Engineering/Biotechnology; Gamma rays; Gravimetric analysis; Industrial Chemistry/Chemical Engineering; Irradiation; Materials Science; Mechanical properties; Original Paper; Packaging materials; Plastics; Polymer Sciences; Polyvinyl alcohol; Polyvinyl alcohols; Radiation; Scanning electron microscopy; Starch; Starches; Sugar; Sugars; Tensile strength; Thermal analysis; Thermal properties; Thin films; Biodegradable materials; Gamma irradiation; Plasticizers; Blend film; Tensile properties
• ISSN: 1566-2543; 1572-8919; 1572-8900
• DOI: 10.1007/s10924-011-0357-6

Blends based on different ratios of starch (35–20%) and plasticizer (sugar; 0–15%) keeping the amount of poly(vinyl alcohol) (PVA) constant, were prepared in the form of thin films by casting solutions. The effects of gamma-irradiation on thermal, mechanical, and morphological properties were investigated. The studies of mechanical properties showed improved tensile strength (TS) (9.61 MPa) and elongation at break (EB) (409%) of the starch-PVA-sugar blend film containing 10% sugar. The mechanical testing of the irradiated film (irradiated at 200 Krad radiation dose) showed higher TS but lower EB than that of the non-radiated film. FTIR spectroscopy studies supported the molecular interactions among starch, PVA, and sugar in the blend films, that was improved by irradiation. Thermal properties of the film were also improved due to irradiation and confirmed by thermo-mechanical analysis (TMA), differential thermo-gravimetric analysis (DTG), differential thermal analysis (DTA), and thermo-gravimetric analysis (TGA). Surface of the films were examined by scanning electron microscope (SEM) image that supported the evidence of crosslinking obtained after gamma irradiation on the film. The water up-take and degradation test in soil of the film were also evaluated. In this study, sugar acted as a good plasticizing agent in starch/PVA blend films, which was significantly improved by gamma radiation and the prepared starch-PVA-sugar blend film could be used as biodegradable packaging materials.