Hydrogen peroxide oxidation of humic acids and lignite

• Published in: Fuel (Guildford) Vol. 134; pp. 406 - 413
• Main Authors: DOSKOCIL, Leoš, GRASSET, Laurent, VALKOVA, Dana, PEKAR, Miloslav
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier 15-10-2014
• Subjects: Applied sciences; Catalysis; Chemical Sciences; Energy; Energy. Thermal use of fuels; Exact sciences and technology; Fuels; Malonic acid; Lignite; Hydrogen; Hydrogen peroxide oxidation; Succinic acid; Oxidation; Peroxides; Humic acids; Humic acid
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2014.06.011

The H2O2 degradation of humic acids and lignite from Mir mine (South Moravian region, Czech Republic) resulted in oxidation of aromatic structures and cleavage of aromatic units. The hydrophilic fraction largely dominated the oxidation digest in both parental materials. The presence of polycyclic biomarkers alpha-Phyllocladane, De-A-lupane confirms the high plant contribution. Hopanoid structures and branched C-15 and C-17 (iso and anteiso) fatty acids show slight bacterial inputs. Short chain n-fatty acids (<C-20) are ubiquitous in living kingdom, whereas long chain homologs are probably derived from higher plants. Phosphoric acid production through the H2O2 oxidation probably results from hydrolyses of pyrophosphate. From hydrophilic fractions of lignite and humic acids, malonic acid and succinic acid are dominant compounds and could indicate that methylene and ethylene chains are main bridge bonds connecting between the aromatic rings in the structure. The H2O2 oxidation of lignite was very selective for producing malonic acid and succinic acid in high yields and the oxidation degradation method appears to be a suitable new way for utilizing South Moravian lignite. For production of malonic acid and succinic acid, the results indicated that the appropriate condition especially was at 50 degrees C for 4 h and 40 degrees C for 4 h, respectively. But oxidation followed by reoxidation of lignite at 30 degrees C for I h could be also a reasonable way to produce that kind of molecules (particularly malonic acid). Lipophilic compounds represented the minor GC-amenable fraction of the total products obtained by oxidation of lignite